chembox verifiedrevid 443875409 Name Iodic acid ImageFile Iodic acid 2D.png ImageSize 200px ImageName Iodic acid ImageFileL1 Iodic acid 3D balls.png ImageSize 1 100px ImageNameL1 Ball and stick model of iodic acid ImageFileR1 Iodic acid 3D vdW.png ImageSizeR1 100px ImageNameR1 Space filling model of iodic acid OtherNames Iodic V acid Section1 Chembox Identifiers ChemSpiderID Ref chemspidercite correct chemspider ChemSpiderID 22761 PubChem 24345 InChI 1 HIO3 c2 1 3 4 h H,2,3,4 InChIKey ICIWUVCWSCSTAQ UHFFFAOYAT ChEBI Ref ebicite correct EBI ChEBI 24857 SMILES O I O O ChEMBL Ref ebicite correct EBI ChEMBL 1161636 StdInChI Ref stdinchicite correct chemspider StdInChI 1S HIO3 c2 1 3 4 h H,2,3,4 StdInChIKey Ref stdinchicite correct chemspider StdInChIKey ICIWUVCWSCSTAQ UHFFFAOYSA N CASNo 7782 68 5 CASNo Ref cascite correct CAS Section2 Chembox Properties Formula HIO sub 3 sub MolarMass 175.91 ... Hydroiodic acid br Iodine pentoxide br Periodic acid Iodic acid , HIO sub 3 sub , can be obtained ... to chloric acid or bromic acid . Iodic acid contains iodine in the oxidation state 5 and it is one of the most stable oxo acids of the halogens in its pure state. When iodic acid is carefully ..., giving a mix of iodine, oxygen and lower oxides of iodine. Preparation Iodic acid can be produced ... Properties Iodic acid is a relatively strong acid with a Acid dissociation constant p K sub a sub of 0.75. It is strongly oxidizing in acidic solution, less so in basic solution. When iodic acid acts ... , iodic acid is reduced to iodine trichloride, a golden yellow compound in solution and no further reduction ... is converted to iodine. Uses Iodic acid is used as a strong acid in analytical chemistry . It may ... orange as the pH indicator indicator . Use in salt industry Iodic acid can be used to synthesize ... hu J dsav nl Waterstofjodaat ja pl Kwas jodowy pt cido i dico ro Acid iodic ru simple Iodic acid fi Jodihappo uk zh ... more details
File iodate anion.svg thumb 140px The iodate anion, IO sub 3 sub sup sup file iodate 3D vdW.png thumb 140px Space filling model of the iodate anion An iodate is a conjugate base of iodic acid . ref http www.m w.com cgi bin dictionary?book Dictionary&va iodate Merriam Webster definition ref In the iodate anion , iodine is bonded to three oxygen atoms and the molecular formula is IO sub 3 sub sup sup . The molecular geometry of iodate is trigonal pyramidal. iodate can be obtained by redox reducing periodate with a thioether . The byproduct of the reaction is a sulfoxide . ref cite journal last Qiu first Chao coauthors Sheng Han Xingguo Cheng and Tianhui Ren year 2005 title Distribution of Thioethers in Hydrotreated Transformer Base Oil by Oxidation and ICP AES Analysis journal Industrial & Engineering Chemistry Research volume 44 issue 11 pages 4151 4155 doi 10.1021 ie048833b url http pubs.acs.org cgi bin abstract.cgi iecred 2005 44 i11 abs ie048833b.html accessdate 2007 05 03 quote Thioethers can be oxidized to sulfoxides by periodate, and periodate is reduced to iodate format abstract ref iodates are a class of chemical compound s containing this group. Examples are sodium iodate NaIO sub 3 sub , silver iodate AgIO sub 3 sub , and calcium iodate Ca IO sub 3 sub sub 2 sub . iodates resemble chlorate s with iodine instead of chlorine. In acid conditions, iodic acid is formed. Potassium hydrogen iodate KH IO sub 3 sub sub 2 sub is a double salt of potassium iodate and iodic acid and an acid as well. Iodates are used in the iodine clock reaction . References reflist Category Oxoanions Category Iodates de Iodate es Yodato fr Iodate nl Jodaat ja pl Pochodne tlenowych kwas w jodu ru simple Iodate fi Jodaatti tr yodat uk zh ... more details
chembox Verifiedfields changed verifiedrevid 464401972 Name Sodium iodate ImageFileL1 Sodium 3D.png ImageNameL1 The sodium cation ImageFileR1 Iodate 3D vdW.png ImageSizeR1 120px ImageNameR1 The iodate anion space filling model OtherNames iodic acid, sodium salt Section1 Chembox Identifiers ChemSpiderID Ref chemspidercite correct chemspider ChemSpiderID 22760 InChI 1 HIO3.Na c2 1 3 4 h H,2,3,4 q 1 p 1 InChIKey WTCBONOLBHEDIL REWHXWOFAB SMILES Na . O I O O StdInChI Ref stdinchicite correct chemspider StdInChI 1S HIO3.Na c2 1 3 4 h H,2,3,4 q 1 p 1 StdInChIKey Ref stdinchicite correct chemspider StdInChIKey WTCBONOLBHEDIL UHFFFAOYSA M CASNo Ref cascite changed ?? CASNo 7681 55 2 PubChem 24344 RTECS NN1400000 Section2 Chembox Properties Formula NaIO sub 3 sub MolarMass 197.8924 g mol Appearance white orthorhombic crystals Density 4.28 g cm , solid Solubility 9.47g 100 mL MeltingPt 425 C decomp ref Citation last Lide first David R. author link last2 first2 author2 link publication date date year 1998 title Handbook of Chemistry and Physics edition 87 volume series publication place Boca Raton, FL place publisher CRC Press id isbn 0 8493 0594 2 doi oclc pages 4 85 url accessdate ref BoilingPt Section7 Chembox Hazards EUClass not listed NFPA H 1 NFPA R 1 NFPA O OX Section8 Chembox Related OtherAnions sodium iodide br sodium periodate br sodium bromate br sodium chlorate OtherCations potassium iodate br silver iodate Sodium iodate Sodium Na Iodine I Oxygen O sub 3 sub is the sodium Salt chemistry salt of iodic acid . Sodium iodate is an oxidizing agent and as such it can cause fires upon contact with combustible materials or reducing agents . Preparation It can be prepared by reacting a sodium containing base such as sodium hydroxide with iodic acid , for example Iodic acid HIO sub 3 sub Sodium hydroxide NaOH NaIO sub 3 sub Water H sub 2 sub O It can also be prepared by adding iodine to a hot, concentrated solution of sodium hydroxide or its Sodium carbonate carbonate 3 iodi ... more details
chembox verifiedrevid 443877513 ImageFile Iodine pentoxide 3D balls.png ImageSize IUPACName diiodine pentoxide OtherNames iodine V oxide iodic anhydride Section1 Chembox Identifiers ChemSpiderID Ref chemspidercite correct chemspider ChemSpiderID 140179 InChI 1 I2O5 c3 1 4 7 2 5 6 InChIKey BIZCJSDBWZTASZ UHFFFAOYAR StdInChI Ref stdinchicite correct chemspider StdInChI 1S I2O5 c3 1 4 7 2 5 6 StdInChIKey Ref stdinchicite correct chemspider StdInChIKey BIZCJSDBWZTASZ UHFFFAOYSA N CASNo 12029 98 0 PubChem ChEBI Ref ebicite correct EBI ChEBI 29914 SMILES O I O OI O O Section2 Chembox Properties Formula I sub 2 sub O sub 5 sub MolarMass 333.81 g mol Appearance white crystalline solid ref name G&E Greenwood&Earnshaw pp. 851 852 ref br hygroscopic Density 4.980 g cm sup 3 sup ref name G&E MeltingPt 300 C decomp ref Pradyot Patnaik. Handbook of Inorganic Chemicals . McGraw Hill, 2002, ISBN 0070494398 ref Solubility SolubleOther soluble in nitric acid br insoluble in ethanol , ether and carbon disulfide CS sub 2 sub Section3 Chembox Hazards MainHazards oxidizer FlashPt Autoignition NFPA H 3 NFPA F 1 NFPA R 0 NFPA O OX Section8 Chembox Related OtherAnions iodine pentafluoride Iodine pentoxide is the chemical compound with the Chemical formula formula I sub 2 sub O sub 5 sub . This iodine oxide is the acid anhydride anhydride of iodic acid . It is produced by dehydrating iodic acid at 200 C in a stream of dry air ref name G&E 2HIO sub 3 sub I sub 2 sub O sub 5 sub H sub 2 sub O Structure I sub 2 sub O sub 5 sub is bent with an I O I angle of 139.2 , but the molecule has no mirror plane so its molecular symmetry symmetry is not C sub 2v sub . The terminal I O distances are around 1.80 and the bridging I O distances are around 1.95 . ref cite journal author K. Selte and A. Kjekshus year 1970 title Iodine oxides part III, The crystal structure of I sub 2 sub O sub 5 sub journal Acta Chem. Scand. volume 24 pages 1912 1914 doi 10.3891 acta.chem.scand.24 1912 ref Reactions Iodine p ... more details
chembox Verifiedfields changed verifiedrevid 464199231 Name Orthoperiodic acid ImageFile Orthoperiodic acid 3D balls.png ImageSize IUPACName OtherNames Paraperiodic acid Section1 Chembox Identifiers ChemSpiderID Ref chemspidercite correct chemspider ChemSpiderID 58684 InChI 1 HIO4 c2 1 3,4 5 h H,2,3,4,5 InChIKey KHIWWQKSHDUIBK UHFFFAOYAH ChEMBL Ref ebicite correct EBI ChEMBL 1161637 StdInChI Ref stdinchicite correct chemspider StdInChI 1S HIO4 c2 1 3,4 5 h H,2,3,4,5 StdInChIKey Ref stdinchicite correct chemspider StdInChIKey KHIWWQKSHDUIBK UHFFFAOYSA N CASNo Ref cascite changed ?? CASNo 10450 60 9 PubChem 65185 ChEBI Ref ebicite correct EBI ChEBI 29149 SMILES OI O O O Section2 Chembox Properties Formula H sub 5 sub IO sub 6 sub MolarMass 227.941 g mol Appearance Colorless crystals Density MeltingPtC 122 BoilingPt Solubility Section3 Chembox Hazards ExternalMSDS http physchem.ox.ac.uk MSDS PE periodic acid.html External MSDS EUClass Oxidizer O , Toxic T , Corrosive C RPhrases R23 R24 R25 R34 R41 NFPA H 3 NFPA F 0 NFPA R 0 NFPA O OX FlashPt Autoignition Periodic acid , ref The name is not derived from period , but from iodine per iodic acid compare iodic acid , perchloric acid , and it is thus pronounced per iodic IPA en p r.a d k respell PURR eye OD ik , and not as IPA en p r d k respell PEER ee OD ik . ref or iodic VII acid ref cite book title Concise Science Dictionary editor Alan Isaacs, John Daintith, Elizabeth Martin publisher Oxford University Press location Oxford year 1984 pages 356 isbn 0192115936 ref is an oxoacid of iodine having chemical formula HIO sub 4 sub or H sub 5 sub IO sub 6 sub . In dilute aqueous solution, periodic acid exists as discrete hydronium H sub 3 sub O sup sup and meta periodate IO sub 4 sub sup sup ions. When more concentrated, orthoperiodic acid , H sub 5 sub IO sub 6 sub , is formed this dissociate s into hydronium and orthoperiodate IO sub 6 sub sup 5 sup ions. In practice, the metaperiodate and orthoperiodate ions co exist ... more details
Infobox Album See Wikipedia WikiProject Albums Name Far Off Grace Type studio Artist Vanden Plas band Vanden Plas Cover Far Off Grace cover.jpg Released September 16, 1999 Recorded Genre Progressive metal Length 59 56 Label InsideOut Records Producer Reviews Last album The God Thing br 1997 This album Far Off Grace br 1999 Next album Spirit of Live br 2000 Far Off Grace is the third full length album by the progressive metal band Vanden Plas band Vanden Plas . Track listing I Can See 4 01 Far Off Grace 7 03 Into the Sun 6 32 Where s the Man 6 10 Inside of Your Head 6 13 Don t Miss You 3 51 Iodic Rain 6 54 Fields of Hope 6 46 I m With You 6 43 Kiss of Death 5 41 References http www.progarchives.com album.asp?id 1648 VANDEN PLAS Far Off Grace reviews and MP3 progarchives.com http www.metal archives.com index.php Encyclopaedia Metallum bands by letter V Vanden Plas Far Off Grace Category 1999 albums Category Vanden Plas albums Category Inside Out Music albums ... more details
Infobox Album See Wikipedia WikiProject Albums Name Spirit of Live Type live Artist Vanden Plas band Vanden Plas Cover Spirit of Live cover.jpg Released September 8th, 2000 Recorded Genre Progressive metal Label InsideOut Records Last album Far Off Grace br 1999 This album Spirit of Live br 2000 Next album Beyond Daylight br 2002 Spirit of Live is the first live album by the progressive metal band Vanden Plas band Vanden Plas . The song Kiss of Death features Don Dokken as guest on lead vocals and Rainmaker features Patrick Rondat as guest on lead guitar. Track listing I Can See 4 26 Into The Sun 7 05 Soul Survives 9 52 How Many Tears 10 37 I Don t Miss You 3 50 Journey to Paris 3 08 Spirit Of Life 4 28 Iodic Rain 6 11 Far Off Grace 9 51 Kiss of Death 5 28 Rainmaker 8 38 Note Kiss Of Death & I Don t Miss You are only included on the European version. The American version features You Fly . Category 2000 live albums Category Vanden Plas albums Category InsideOut Music live albums ... more details
chembox verifiedrevid 434366230 ImageFile Potassium iodate unit cell 3D balls.png ImageFile2 Jodi nan draseln .JPG IUPACName Potassium iodate OtherNames Iodic acid, potassium salt Section1 Chembox Identifiers ChemSpiderID Ref chemspidercite correct chemspider ChemSpiderID 22856 UNII Ref fdacite correct FDA UNII I139E44NHL InChI 1 HIO3.K c2 1 3 4 h H,2,3,4 q 1 p 1 InChIKey JLKDVMWYMMLWTI REWHXWOFAL SMILES K . O I O O StdInChI Ref stdinchicite correct chemspider StdInChI 1S HIO3.K c2 1 3 4 h H,2,3,4 q 1 p 1 StdInChIKey Ref stdinchicite correct chemspider StdInChIKey JLKDVMWYMMLWTI UHFFFAOYSA M CASNo 7758 05 6 CASNo Ref cascite correct CAS PubChem 24448 Section2 Chembox Properties Formula KIO sub 3 sub MolarMass 214.001 g mol Appearance white crystalline powder Density 3.89 g cm sup 3 sup Solubility 4.74 g 100 mL 0 C br 32.3 g 100 mL 100 C SolubleOther soluble in potassium iodide KI solution br insoluble in alcohol , liquid ammonia MeltingPt 560 C decomp. Section7 Chembox Hazards ExternalMSDS EUIndex Oxidant O RPhrases R9 , R22 , R36 , R37 , R38 SPhrases S35 NFPA H 2 NFPA F 0 NFPA R 1 NFPA O FlashPt Non flammable Section8 Chembox Related OtherAnions Potassium chlorate br Potassium bromate OtherCations Sodium iodate OtherCpds Potassium iodide br Potassium periodate Potassium iodate Potassium K Iodine I Oxygen O sub 3 sub is a chemical compound . It is Ionic compound ionic , made up of K sup sup ions and IO sub 3 sub sup sup ions in a 1 1 ratio. Chemical properties Potassium iodate is an oxidizing agent and as such it can cause fires if in contact with combustible materials or reducing agents . It can be prepared by reacting a potassium containing base such as potassium hydroxide with iodic acid , for example Iodic acid HIO sub 3 sub Potassium hydroxide KOH KIO sub 3 sub Water H sub 2 sub O It can also be prepared by adding iodine to a hot, concentrated solution of potassium hydroxide. 3 iodine I sub 2 sub 6 Potassium hydroxide KOH KIO sub 3 sub 5 potassium iodide KI 3 w ... more details
In organic chemistry , an electrophilic aromatic halogenation is a type of electrophilic aromatic substitution . This organic reaction is typical of aromatic compounds and a very useful method for adding substituents to an aromatic system. Image OChem Reaction HalogenationBenzene.png 400px Halogenation of Benzene where X is the halogen, catalyst represents the catalyst if needed and HX represents the protonated base. A few types of aromatic compounds, such as phenol , will react without a catalyst , but for typical benzene derivatives with less reactive substrates, a Lewis acid catalyst is required. Typical Lewis acid catalysts include AlCl sub 3 sub , FeCl sub 3 sub , FeBr sub 3 sub , and ZnCl sub 2 sub . These work by forming a highly electrophile electrophilic complex chemistry complex which attacks the benzene ring. Reaction mechanism The reaction mechanism for chlorination of benzene is the same as bromination of benzene. iron III bromide Ferric bromide and iron III chloride ferric chloride become inactivated if they react with water, including moisture in the air. Therefore, they are generated by adding iron fillings to bromine or chlorine. Here is the mechanism of this reaction Image Chem Mech BrominationBenzene.png 700px The mechanism for bromination of benzene The mechanism for iodination is slightly different iodine I sub 2 sub is treated with an oxidizing agent such as nitric acid to obtain the electrophilic iodine 2 I sup sup . Unlike the other halogens, iodine does not serve as a base since it is positive. In one study the iodinization reagent is a mixture of iodine and iodic acid . ref Regioselective iodination of hydroxylated aromatic ketones Bhagwan R. Patila, Sudhakar R. Bhusarec, Rajendra P. Pawara, and Yeshwant B. Vibhute b Arkivoc 2006 i 104 108. http www.arkat usa.org ark journal 2006 I01 General 1607 05 1607J 20as 20published 20mainmanuscript.asp Online Article ref In another series of studies the powerful reagent obtained by using a mixture of ... more details
The Bray Liebhafsky reaction is a chemical clock first described by William C. Bray in 1921 and the first oscillating reaction in a stirred homogeneous solution. ref cite journal doi 10.1021 ja01439a007 year 1921 author Bray, William C. journal Journal of the American Chemical Society volume 43 pages 1262 issue 6 ref He investigated the role of the iodate IO sub 3 sub sup sup , the anion of iodic acid in the catalytic conversion of hydrogen peroxide to oxygen and water by the iodate. He noticed that the concentration of iodine molecules oscillated and that oxygen did build up pulsating. An increase in temperature reduces the cycle in the range of hours. This oscillating reaction consisting of free radical on non radical steps was investigated further by his student Herman A. Liebhafsky, ref cite journal doi 10.1021 ja01352a006 year 1931 last1 Bray first1 William C. last2 Liebhafsky first2 Herman A. journal Journal of the American Chemical Society volume 53 pages 38 44 ref hence the name Bray Liebhafsky reaction. During this period, most chemists rejected the phenomenon and tried to explain the oscillation by invoking heterogeneous impurities. A fundamental property of this system is that hydrogen peroxide has a redox potential which enables the simultaneous oxidation of iodine to iodate 5 H sub 2 sub O sub 2 sub I sub 2 sub 2 IO sub 3 sub sup sup 2 H sup sup 4 H sub 2 sub O and the Redox reduction of iodate back to iodine 5 H sub 2 sub O sub 2 sub 2 IO sub 3 sub sup sup 2 H sup sup I sub 2 sub 5 O sub 2 sub 6 H sub 2 sub O Between these two reactions the system oscillates causing a concentration jump of the iodide and the oxygen production. The net reaction is 2 H sub 2 sub O sub 2 sub 2 H sub 2 sub O O sub 2 sub necessitating a catalyst and IO sub 3 sub sup sup . References references cite journal doi 10.1021 j100145a039 title A new explanation of the oscillations in the Bray Liebhafsky reaction year 1993 author Ludovit Treindl Richard M. Noyes journal The Journal ... more details
Chembox verifiedrevid 443875808 ImageFileL1 Iodine pentafluoride gas 2D dimensions.png ImageNameL1 Stereo structural formula of iodine pentafluoride ImageFileR1 Iodine pentafluoride 3D vdW.png ImageNameR1 Spacefill model of iodine pentafluoride PIN Iodine V fluoride SystemticName Pentafluoro sup 5 sup iodane OtherNames Iodic fluoride Section1 Chembox Identifiers InChI1 1 F5I c1 6 2,3,4 5 InChIKey1 PJIYEPACCBMRLZ UHFFFAOYAU CASNo 7783 66 6 PubChem 522683 PubChem Ref Pubchemcite ChemSpiderID 455940 ChemSpiderID Ref chemspidercite correct chemspider EINECS 232 019 7 StdInChI Ref stdinchicite correct chemspider StdInChI 1S F5I c1 6 2,3,4 5 StdInChIKey Ref stdinchicite correct chemspider StdInChIKey PJIYEPACCBMRLZ UHFFFAOYSA N SMILES FI F F F F InChI 1S F5I c1 6 2,3,4 5 InChIKey PJIYEPACCBMRLZ UHFFFAOYSA N Section2 Chembox Properties Formula IF sub 5 sub MolarMass 221.89 g mol Appearance pale yellow liquid Density 3.250 g cm sup 3 sup Solubility reacts ref Pradyot Patnaik. Handbook of Inorganic Chemicals . McGraw Hill, 2002, ISBN 0070494398 ref MeltingPtC 9.43 BoilingPtC 97.85 pKa pKb Viscosity Section3 Chembox Structure MolShape Square pyramidal molecular geometry square pyramidal ref name Durbank cite journal title Crystal structure of iodine pentafluoride at 80.deg. author R. D. Durbank, G. R. Jones journal Inorganic Chemistry journal Inorganic Chemistry year 1974 volume 13 issue 5 pages 421 439 doi 10.1021 ic50135a012 ref Coordination square pyramidal CrystalStruct monoclinic br Crystallographic point group point group C2 c Dipole Section7 Chembox Hazards ExternalMSDS http www.solvaychemicals.us static wma pdf 5 1 8 1 IF5.pdf External MSDS MainHazards toxic, oxidizer, corrosive NFPA H 4 NFPA F 0 NFPA R 1 NFPA O W Section8 Chembox Related OtherAnions Diiodine pentoxide OtherCations Bromine pentafluoride OtherCpds Iodine trifluoride , Iodine heptafluoride Iodine pentafluoride is an interhalogen compound with chemical formula IF sub 5 sub . It is a fluoride of iodine ... more details
ref Ortho periodic acid ref group note The name is not derived from period , but from iodine per iodic acid compare iodic acid , perchloric acid , and it is thus pronounced per iodic IPAc en p r . a ... more details
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